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Benario

Potassium Citrate Monohydrate (Food Grade) — Buffer, Emulsifier & Mineral Salt

Potassium Citrate Monohydrate (Food Grade) — Buffer, Emulsifier & Mineral Salt

Regular price $9.00 AUD
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🔬Lab-tested≥99.0% purity
📦Packed in AustraliaSame-week dispatch
FSANZ E332383mg K per gram
🏭500+ businessesTrust AuSaMicS
Food Grade E332 FSANZ Approved 383mg K per gram COA Available

Potassium Citrate Monohydrate (E332) is a versatile food-grade potassium salt of citric acid — used as a buffering agent, emulsifier, sequestrant, acidity regulator and mineral source. Approved under FSANZ Standard 1.3.1, it is widely used in sports drinks and electrolyte formulas as a bioavailable potassium source, in processed cheese as an emulsifying salt, in jams and confectionery for pH control, and in food manufacturing for its excellent buffering capacity at near-neutral pH.

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Backed by AuSaMicS Pty Ltd — Australian manufacturer and supplier of food-grade ingredients trusted by 500+ Australian businesses. Every batch lab-tested before dispatch.
Popular uses
Electrolyte DrinksPotassium source in sports & hydration drinks
🧀Processed CheeseEmulsifying salt, pH control, smooth melt
🍓Jams & PreservespH buffering, pectin activation, preservation
🥤BeveragesAcidity regulation, mineral fortification
🍬ConfectionerypH control, sequestrant, texture improvement
🏭Food ManufacturingBuffer, emulsifier, sequestrant, anti-oxidant synergist
Why Benario Potassium Citrate Monohydrate
  • FSANZ Standard 1.3.1 approved (E332) — legal for use in Australian food products
  • ≥99.0% purity — lab-tested, Certificate of Analysis available on request
  • Excellent potassium source — 38.3% potassium content by weight (highly bioavailable)
  • Buffering capacity at pH 5.5–8.5 — ideal for near-neutral food and beverage applications
  • Packed in Australia — quality-checked before every dispatch
  • Three sizes: 200g, 500g and 1kg
  • Freely water soluble — easy to incorporate into liquid and dry formulations
Quick reference
Property Detail
E number E332(iii) — Tripotassium citrate
Also known as Tripotassium citrate monohydrate, potassium citrate, E332(iii), INS 332(iii)
Chemical formula C₆H₅K₃O₇·H₂O
Form White crystalline powder or granules
Purity ≥ 99.0%
Potassium content ~38.3% by weight (~383mg K per gram)
pH (1% solution) ~8.0 – 9.0 (alkaline)
Solubility Freely soluble in water
Pack sizes 200g · 500g · 1kg
Shelf life 24 months (sealed, cool & dry)
Standard FSANZ E332, EU E332(iii), FCC, GRAS
💡 Potassium content: Each gram of Potassium Citrate Monohydrate provides approximately 383mg of potassium — a highly bioavailable form preferred over Potassium Chloride for food and beverage applications due to its superior taste profile.

Benario is a trading name of AuSaMicS Pty Ltd (ABN 56 676 640 467). This product is intended for use as a food ingredient in accordance with FSANZ Standard 1.3.1. Always use within permitted levels for the relevant food category. This product is not a therapeutic good.

Potassium Citrate Monohydrate is most widely used in electrolyte drinks and processed cheese — two very different applications that both benefit from its combination of buffering capacity, mineral content and excellent solubility.

Recommended usage levels
Application Usage level Notes
Sports / electrolyte drink 0.1 – 0.5% Potassium source; mild alkaline buffer — dissolve in water
Processed cheese / cheese sauce 1 – 3% Emulsifying salt alongside sodium citrate
Jams & preserves 0.1 – 0.3% pH buffering and pectin activation
Beverages / pH regulation 0.05 – 0.3% Adjust acidity; neutralises citric acid sharpness
Confectionery / hard candy 0.1 – 0.5% Sequestrant and pH control
Fermentation media 0.1 – 0.5% Potassium and citrate source for culture media
Antioxidant synergist 0.01 – 0.1% Chelates metals; enhances antioxidant effectiveness
General pH buffering As per formulation Target pH 5.5–8.5; verify with calibrated meter
Potassium sources comparison
Ingredient K content Taste Best for
Potassium Citrate (E332) ~38.3% Mild, pleasant Sports drinks, cheese, food
Potassium Chloride (E508) ~52.4% Bitter, metallic Salt substitute (masked)
Potassium Bicarbonate (E501) ~39.1% Slightly salty Leavening, pH adjustment
Potassium Phosphate (E340i) ~28.7% Mild Buffering, mineral source
💡 Formulation tip: Potassium Citrate is the preferred potassium source for sports and electrolyte drinks — it is better tolerated than Potassium Chloride (which can taste bitter) and provides both potassium and citrate in a single ingredient. A typical electrolyte formula combines Potassium Citrate with Sodium Citrate and Sodium Chloride for a balanced electrolyte profile. For processed cheese, combine with Sodium Citrate (E331) in a 1:2 ratio for an emulsifying salt blend that controls both pH and melt behaviour.
Dissolution & handling
  • Dissolve in warm water (40–60°C) with stirring for fastest dissolution
  • Fully water soluble — solutions should be clear
  • Verify pH after dissolution with a calibrated pH meter
  • For pH neutralisation of citric acid, add Potassium Citrate gradually until target pH is reached
  • Prepared solutions are stable for up to 2 weeks refrigerated in sealed containers
  • Slightly hygroscopic — keep container sealed to prevent caking
Storage
  • Store in a cool, dry place away from direct sunlight and moisture
  • Keep container tightly sealed — slightly hygroscopic
  • Shelf life: 24 months from manufacture date when stored correctly
  • Keep away from strong acids and oxidising agents

Usage levels are indicative. Always comply with FSANZ Standard 1.3.1 permitted levels. AuSaMicS Pty Ltd accepts no responsibility for use outside recommended guidelines.

Technical specifications
Parameter Specification
Chemical name Tripotassium 2-hydroxypropane-1,2,3-tricarboxylate monohydrate
Chemical formula C₆H₅K₃O₇·H₂O
CAS number 6100-05-6
E number E332(iii)
INS number INS 332(iii)
Molecular weight 324.41 g/mol
Potassium content ~38.3% (w/w)
Appearance White crystalline powder or granules
Assay (purity) ≥ 99.0% (on dried basis)
Water content 5.0 – 7.0% (as monohydrate)
pH (1% solution) 8.0 – 9.0
Insoluble matter ≤ 0.05%
Fluoride ≤ 10 mg/kg
Heavy metals (as Pb) ≤ 5 mg/kg
Arsenic ≤ 1 mg/kg
Lead ≤ 0.5 mg/kg
Applicable standard FSANZ Standard 1.3.1 (E332), FCC 12th Ed., EU E332(iii), JECFA
International approvals
Market Code / Name Status
Australia / NZ (FSANZ) E332 — Potassium citrates Approved
European Union E332(iii) — Tripotassium citrate Approved
United States (FDA) GRAS — Generally Recognised as Safe Approved
INS (Codex) INS 332(iii) Approved
FCC Grade Meets Food Chemicals Codex specifications Confirmed
Pack sizes & pricing
Size Price (AUD) Best for
200g $16.90 R&D, home use, testing
500g $29.90 Small commercial, regular use
1kg $49.90 Commercial production, food manufacturers

COA available on request — info@benario.com.au

Specifications represent typical values. Batch-specific results confirmed in COA.

Potassium Citrate Monohydrate (E332) has an excellent safety profile. Approved under FSANZ Standard 1.3.1. Produces an alkaline solution — handle with standard precautions for alkaline salts.

Key safety points
  • Approved food additive — FSANZ E332, EU E332(iii), GRAS (USA), FCC compliant
  • No known common allergens — gluten-free, vegan and vegetarian suitable
  • Alkaline in solution (~pH 8–9) — avoid prolonged eye contact with concentrated solutions
  • Contains potassium — people on potassium-restricted diets should consult a healthcare professional
  • This product is a food-grade ingredient, not a therapeutic good
  • Store away from strong acids — incompatible with concentrated acids
First aid
Route Action
Skin contact Wash with soap and water. No significant risk at food-grade handling quantities.
Eye contact Rinse with clean water for 15 minutes. Seek medical advice if irritation persists.
Ingestion Food-grade ingredient — no significant risk at normal quantities. Seek medical advice if large quantities ingested.
Inhalation Move to fresh air. Seek medical advice if symptoms persist.
GHS classification
Hazard category Classification
Physical hazards Not classified
Health hazards Not classified at food-grade handling quantities
Environmental hazards Not classified
Signal word None required

Full SDS available on request — info@benario.com.au

This is a general safety summary only. For commercial use, request the full SDS. AuSaMicS Pty Ltd (ABN 56 676 640 467) accepts no liability for misuse of this product.

Frequently asked questions
Potassium Citrate Monohydrate (E332) is used as a buffering agent to control and stabilise pH, as an emulsifying salt in processed cheese, as a bioavailable potassium source in sports and electrolyte drinks, as a sequestrant to chelate metal ions and prevent oxidation, and as a pectin activator in jams and preserves. It is one of the most versatile potassium salts in food manufacturing.
Potassium Citrate Monohydrate contains approximately 38.3% potassium by weight. This makes it a highly concentrated and bioavailable potassium source compared to Potassium Chloride (52.4% K but poor taste) or Potassium Bicarbonate (39.1% K). For electrolyte formulation, 1g of Potassium Citrate Monohydrate provides approximately 383mg of potassium.
Potassium Citrate (E332) and Sodium Citrate (E331) are structurally similar — both are citrate salts used as buffers, emulsifiers and sequestrants. The key difference is the cation: Potassium Citrate provides potassium, while Sodium Citrate provides sodium. Both are used together in electrolyte drinks and processed cheese formulas. Sodium Citrate is more widely used and slightly less expensive; Potassium Citrate is essential where potassium fortification is required.
A 1% solution of Potassium Citrate Monohydrate produces a pH of approximately 8.0–9.0 (alkaline). It acts as an effective buffer across pH 5.5–8.5. To achieve a specific target pH, combine with Citric Acid and adjust to the desired level using a calibrated pH meter.
Yes. Potassium Citrate is approved under FSANZ Standard 1.3.1 as E332. It is also approved in the EU as E332(iii), GRAS in the USA and listed in the Codex Alimentarius as INS 332(iii). It is one of the most widely approved potassium salts in global food regulation.
Yes. Email info@benario.com.au with your order number for a batch-specific Certificate of Analysis including assay, potassium content, heavy metals and identity confirmation.
The 200g pack suits home brewers, R&D applications and small-batch testing. The 500g and 1kg are ideal for regular commercial production, sports nutrition manufacturers and food producers.

Have a question not answered here? Contact us at info@benario.com.au — we typically respond within 1 business day.

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